This may be a user error on our part or a disagreement about the interpretation of the CODEOWNER spec.
If I have a CODEOWNERS file with the first line of / it doesn't match anything. Accord to one part of the spec, having a path ending with a / should match everything in the directory, and all sub-directories. By extension just a / should match everything in the repository.
from codeowners import CodeOwners
code_file = '''
... / @ORG/MyTeam
... '''
codeowner = CodeOwners(code_file)
codeowner.of("build.config")
[]